Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
نویسندگان
چکیده
The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa-hedral. The anions are connected by the lattice water mol-ecule through O-H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H⋯O and C-H⋯Cl inter-actions.
منابع مشابه
Bis(tetramethylammonium) oxalate monohydrate
In the crystal structure of the title hydrated salt, 2C(4)H(12)N(+)·C(2)O(4) (2-)·H(2)O, the two independent cations, the anion and the water mol-ecule all lie on special positions of m site symmetry. In both cations, the mirror plane passes through the nitrogen atom and two methyl groups; in the anion, the mirror plane passes through two carbon and two oxygen atoms. The anions and water mol-ec...
متن کاملCrystal structure of the monoclinic phase (phase IV) of bis(tetramethylammonium) tetrachloridocuprate(II)
The crystal structure of the low-temperature monoclinic phase of the title compound, [(CH3)4N]2[CuCl4], was determined at 120 K. The structure of the room-temperature phase has been determined in the ortho-rhom-bic space group Pmcm [Morosin & Lingafelter (1961 ▸). J. Phys. Chem. 50-51; Clay et al. (1975 ▸). Acta Cryst. B31 289-290]. The asymmetric unit consists of one discrete tetra-chlorido-cu...
متن کاملCrystal structures of tetramethylammonium (2,2′-bipyridine)tetracyanidoferrate(III) trihydrate and poly[[(2,2′-bipyridine-κ2 N,N′)di-μ2-cyanido-dicyanido(μ-ethylenediamine)(ethylenediamine-κ2 N,N′)cadmium(II)iron(II)] monohydrate]
The crystal structures of the building block tetra-methyl-ammonium (2,2'-bi-pyridine-κ(2) N,N')tetra-cyanidoferrate(III) trihydrate, [N(CH3)4][Fe(CN)4(C10H8N2)]·3H2O, (I), and a new two-dimensional cyanide-bridged bimetallic coordination polymer, poly[[(2,2'-bi-pyridine-κ(2) N,N')di-μ2-cyanido-dicyanido(μ-ethyl-enedi-amine-κ(2) N:N')(ethyl-enedi-amine-κ(2) N,N')cadmium(II)iron(II)] monohydrate]...
متن کاملcis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa-hedral geometry by four N atoms from two 4,4'-dimethyl-2,2'-bipyridine ligands, one O atom and one Cl atom. In the crystal, O-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distances = 3.7236 (17) and 3.6026 (19) Å] stab...
متن کامل(Acetato-κO)(2,2′-bipyridine-κ2 N,N′)trimethylplatinum(IV) monohydrate
In the title hydrate, [Pt(CH(3))(3)(CH(3)COO)(C(10)H(8)N(2))]·H(2)O, the Pt(IV) atom exhibits a distorted octa-hedral coordination geometry built up by three methyl ligands in a facial arrangement, a bipyridine ligand and a monodentately bound acetate ligand. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds are observed between the water mol-ecule and the platinum complex, which l...
متن کامل